Poly(vinylferrocene)/Cellulose Acetate Fibers: A New Approach for In-Situ Monitoring Process Through QCM and Electrospinning Studies
Journal of Inorganic and Organometallic Polymers and Materials, cilt.25, sa.3, ss.544-550, 2015 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 25 Sayı: 3
- Basım Tarihi: 2015
- Doi Numarası: 10.1007/s10904-014-0114-0
- Dergi Adı: Journal of Inorganic and Organometallic Polymers and Materials
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.544-550
- Anahtar Kelimeler: Cellulose acetate, Electrospinning, Poly(vinylferrocene), Quartz crystal microbalance (QCM)
- Isparta Uygulamalı Bilimler Üniversitesi Adresli: Hayır
Özet
A poly(vinylferrocene) (PVFc)/cellulose acetate (CA) fibers were obtained using an electrospinning method. The electrospinning process was controlled in situ with a quartz crystal microbalance (QCM) system. Fiber formation was observed through adjusting PVFc concentration. Morphological characteristics depending on the changes of atomic % ratio value of PVFc/CA electrospun fibers was investigated by scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy analysis. Electrochemical behavior of PVFc/CA electrospun fibers was investigated by using cyclic voltammetry measurements based on the Fc+/Fc redox couple. The results indicated that PVFc deployed in/on the CA fibers and aggregated arbitrarily on the QCM electrode. The new PVFc/CA electrospun fibers were used for anion sensing.