The Effect of Electrospun PMMA/rGO Fiber Addition on the Improvement of the Physical and Mechanical Properties of PMMA Resin


Elmas Alsini T. G., KÜRKÇÜOĞLU I., Nohut Maslakci N., Uygun Oksuz A.

Prosthesis, vol.7, no.4, 2025 (ESCI, Scopus) identifier

  • Publication Type: Article / Article
  • Volume: 7 Issue: 4
  • Publication Date: 2025
  • Doi Number: 10.3390/prosthesis7040079
  • Journal Name: Prosthesis
  • Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
  • Keywords: autopolymerizing PMMA, electrospinning, fiber, flexural strength, graphene oxide, reinforced resin
  • Isparta University of Applied Sciences Affiliated: No

Abstract

Background/Objectives: Autopolymerizing poly (methyl methacrylate) (PMMA) resin is widely used in provisional restorations; however, its inadequate mechanical properties represent a significant limitation. This study aimed to develop electrospun fibers with chemically reduced graphene oxide (rGO) and to evaluate the effect of fiber reinforcement on the mechanical and physical properties of a commercially available PMMA resin. Methods: Electrospinning was employed to produce nanofibers containing 0.02 wt% and 0.05 wt% rGO within a PMMA matrix. Fiber characterization was performed using SEM-EDS, XRD, TGA/DTG, and FTIR. Following characterization, the fibers were blended into PMMA resin at 1%, 2.5%, and 5% (by weight). The resulting fiber-reinforced composites were tested for flexural strength, elastic modulus, surface roughness, and Vickers microhardness. Results: The addition of 1% and 2.5% PMMA/rGO-0.02 fibers and 1% PMMA/rGO-0.05 fibers significantly improved the flexural strength of PMMA compared with the control group (p < 0.05). A statistically significant increase in elastic modulus was observed only in the group containing 1% PMMA/rGO-0.02 fibers (p < 0.05). However, there were no significant differences in surface roughness or microhardness between the control and experimental groups (p > 0.05). Conclusions: Incorporating electrospun PMMA-rGO fibers into PMMA resin enhances flexural properties at low concentrations without altering surface characteristics. These findings suggest that such fiber-reinforced systems hold promises for improving the mechanical performance and functional longevity of provisional dental restorations under clinical conditions.