The production route of the MASnBr3 based perovskite solar cells with fully ultrasonic spray pyrolysis method


KALELİ M., Şen E., Lapa H. E., ALDEMİR D. A.

Physica B: Condensed Matter, vol.645, 2022 (SCI-Expanded, Scopus) identifier

  • Publication Type: Article / Article
  • Volume: 645
  • Publication Date: 2022
  • Doi Number: 10.1016/j.physb.2022.414293
  • Journal Name: Physica B: Condensed Matter
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Chemical Abstracts Core, Communication Abstracts, INSPEC, Metadex, Civil Engineering Abstracts
  • Keywords: Lead-free, Perovskite solar cells, Spray coating, Ultrasonic spray pyrolysis
  • Isparta University of Applied Sciences Affiliated: No

Abstract

Lead-free FTO/TiO2/MASnBr3/P3HT/Ag perovskite solar cells (PSCs) were fabricated by a fully ultrasonic spray pyrolysis (USP) method. The MASnBr3 thin films had very large grains (clusters) up to 15 μm. The crystal/crystallite size of the films was determined from the XRD pattern as 112.7 nm. The coating of MASnBr3 and P3HT layers was carried out on a large area of 36 cm2. The champion cell with an active area of 0.30 cm2 has an open circuit voltage of 0.370 V, a short circuit of 0.460 mA/cm2, a fill factor of 57.2%, and a power conversion efficiency of 0.097%. The production of all layers with the USP method is important to the commercialization of the lead-free PSCs.