Electrospun plasma-modified chitosan/poly(ethylene terephthalate)/ferrocenyl-substituted N-acetyl-2-pyrazoline fibers for phosphate anion sensing

NOHUT MAŞLAKCI N., EREN E., Topel S. D., Cin G. T., Oksuz A. U.

Journal of Applied Polymer Science, cilt.133, sa.17, 2016 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 133 Sayı: 17
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1002/app.43344
  • Dergi Adı: Journal of Applied Polymer Science
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Anahtar Kelimeler: blends, electrochemistry, electrospinning, fibers, inorganic polymers
  • Isparta Uygulamalı Bilimler Üniversitesi Adresli: Hayır

Özet

Two ferrocenyl-substituted N-acetyl-2-pyrazolines, N-acetyl-3-(2-furyl)-5-ferrocenyl-2-pyrazoline (Fc-1) and N-acetyl-3-(2-thienyl)-5-ferrocenyl-2-pyrazoline (Fc-2) electrospun fibers, were produced in the presence of plasma-modified chitosan (PMCh)/poly(ethylene terephthalate) (PET) supporting polymers with an electrospinning method. The morphological and chemical characterizations of the PMCh/PET/Fc-1 and PMCh/PET/Fc-2 electrospun fibers were determined by scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy analysis. Thermogravimetric analysis results indicated the presence of ferrocene within the PMCh/PET nanofibers. The electrochemical behavior of the PMCh/PET/Fc-1 and PMCh/PET/Fc-2 electrospun fibers were investigated by cyclic voltammetry measurements based on the ferrocene/ferrocenium redox couple. The new PMCh/PET/Fc-1 and PMCh/PET/Fc-2 electrospun fibers aggregated on the indium tin oxide were used for phosphate anion sensing. The highest oxidation peak currents were observed for the PMCh/PET/Fc-1 electrospun fibers at about 0.56 V in 0.1M phosphate buffer.